21. The Final Match Rikkai Second feat. The Rivals (FMR-S)

Seigaku Regulars

Echizen Ryoma played by Takahashi Ryuuki

Tezuka Kunimitsu played by Baba Ryoma

Fuji Syusuke played by Hashimoto Taito

Oishi Shuichiro played by Tsujimoto Yuki

Kikumaru Eiji played by Takazaki Shouta

Momoshiro Takeshi played by Nobeyama Toshihiro

Inui Sadaharu played by Arai Yusuke

Kaidoh Kaoru played by Hayashi Akihiro

Kawamura Takashi played by Chou Ikko

Ichinen Trio

Horio Satoshi played by Maruyama Shun

Kato Kachiro played by Hirai Hiroki

Mizuno Katsuo played by Takahashi Rie

Rikkai

Yukimura Seiichi played by Masuda Toshiki

Sanada Genichirou played by Kanesaki Kentarou

Yagyuu Hiroshi played by Baba Toru & Onoda Ryuunosuke

Niou Masaharu played by Nakagauchi Masataka & Wada Taisuke

Yanagi Renji played by Yamaoki Yuuki

Kirihara Akaya played by Ookawa Genki & Nishimura Mitsuaki

Marui Bunta played by Akaba Mio

Kuwahara Jackal played by Toda Shingo

Fudomine

Ibu Shinji played by Motohiro Oota

St. Rudolph

Fuji Yuuta played by KENN

Yamabuki

Akutsu Jin played by JURI & Shimizu Ryotaro

Hyoutei

Atobe Keigo played by Kubota Yuki

Hiyoshi Wakashi played by Hosogai Kei

Higa

Tanishi Kei played by Matsuzaki Yutaka

Shitenhouji

Tooyama Kintaro played by Kido Yuuya & Kawada Kouya

Shiraishi Kuranosuke played by Harukawa Kyousuke & Sasaki Yoshihide

Others

Echizen Nanjirou played by Ueshima Yukio & Motoyama Shinnosuke

============================================================

01. Matchpoint

>>>>sung by the Seigaku Regulars

02. Highlight

>>>>sung by Seigaku, Rikkai and Shitenhouji Regulars

03. Boku wa Dare?

>>>>sung by Takahashi Ryuuki [Echizen Ryouma]

04. Omoidase Echizen 2

>>>>sung by Takahashi Ryuuki, Nobeyama Toshihiro, Arai Yusuke & Hayashi Akihiro [Echizen, Momoshiro, Inui & Kaidoh]

05. Arata na Sekai e

>>>>sung by Takahashi Ryuuki [Echizen Ryouma]

06. Rivals

>>>>sung by Takahashi Ryuuki, Motohiro Oota, KENN, JURI & Hosogai Kei [Echizen, Ibu, Yuuta, Akutsu & Hiyoshi] + Ichinen Trio

07. Seisei Doudou

>>>>sung by Kanesaki Kentarou [Sanada Genichirou]

08. Rivals, Atobe

>>>>sung by Kubota Yuki [Atobe Keigo] + Rivals and Ichinen Trio

09. Kami no Ko

>>>>sung by the Shitenhouji and Rikkai Regulars

10. Dead End

>>>>sung by the Rikkai Regulars

11. Ore wa Iku

>>>>sung by Takahashi Ryuuki [Echizen Ryouma]

12. Shinogi wo Kezuru Mono-tachi

>>>>sung by Kanesaki Kentarou [Sanada Genichirou] + Rivals and Shitenhouji Regulars

13. Saishuu Kessen

>>>>sung by the entire cast

14. Kore de Mou Owari Kai?

>>>>sung by Masuda Toshiki [Yukimura Seiichi]

15. Level Up

>>>>sung by the Seigaku Regulars minus Echizen

16. Yukimura no Tennis

>>>>sung by the Rikkai Regulars

17. Kurayami ~ Boku wa Dare? (reprise)

>>>>sung by Takahashi Ryuuki [Echizen Ryouma]

18. Ten'imuhou no Kiwami

>>>>sung by the entire cast

19. Omae wa Prince

>>>>sung by the Seigaku Regulars

20. BANZAI

>>>>sung by the Seigaku Regulars

21. GRADUATION

>>>>sung by the entire cast

22. This is the Prince of Tennis

>>>>sung by the entire cast

23. DESTINY

>>>>sung by the Seigaku Regulars (fifth cast ballad)

24. On My Way

>>>>sung by the entire cast

25. F-G-K-S

>>>>sung by the entire cast

======

Cast List from Wikipedia (yes, unreliable as it sometimes is, this is right on point 90% of the time).

Music List from tenipuri_myu LJ community~