02.Remarkable 1st Match Fudomine (RMF)

Seigaku Regulars

Echizen Ryoma played by Kimeru*

Tezuka Kunimitsu played by Takigawa Eiji

Fuji Syusuke played by Nagayama Takashi

Oishi Shuichiro played by Tsuchiya Yuichi

Kikumaru Eiji played by Ichitaro Yamazaki

Momoshiro Takeshi played by Moriyama Eiji

Inui Sadaharu played by Aoyama Sota

Kaidoh Kaoru played by Gomoto Naoya

Kawamura Takashi played by Abe Yoshitsugu

*Yanagi got into an accident two weeks before the premiere, having Kimeru, an understudy to the character of Echizen, take his place while Nagayama shifted to Fuji, and Ichitaro returned as Kikumaru.

Ichinen Trio

Horio Satoshi played by Ishibashi Yusuke

Kato Kachiro played by Toyonaga Toshiyuki

Mizuno Katsuo played by Hotta Masaru

Fudomine

Tachibana Kippei played by Sugawara Takuma

Ibu Shinji played by Konishi Ryosei

Kamio Akira played by Yasuyuki Matsui

Ishida Tetsuya played by Miyano Mamoru

Sakurai Masaya played by Takagi Shun

Others

Echizen Nanjiroh played by Ueshima Yukio

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01. The Regulars ~ This is the Prince of Tennis ~ Victory

>>>>sung by the Seigaku Regulars

02. Yappa Otoko wa Doubles Deshou!

>>>>sung by Kimeru & Moriyama Eiji [Echizen & Momoshiro]

03. Chiku Yosen 1

>>>>sung by the Ichinen Trio

04. Makezu Kirai

>>>>sung by Seigaku Regulars

05. Chiku Yosen 2

>>>>sung by the Ichinen Trio

06. Victory

>>>>sung by the Seigaku Regulars

07. Golden Pair

>>>>sung by Tsuchiya Yuichi & Ichitaro Yamazaki [Oishi & Kikumaru]

08. Shiken Shoubu to wa Sou Iu Koto

>>>>sung by the Fudomine Regulars

09. Challenge ~ Subete wa Shouri no Tame ni

>>>>sung by the Seigaku & Fudomine Regulars

10. Rhythm ni Noru ze

>>>>sung by Yasuyuki Matsui [Kamio Akira]

11. Tough

>>>>sung by Gomoto Naoya [Kaidoh Kaoru]

12. Spot wo Nerae

>>>>sung by Konishi Ryosei [Ibu Shinji]

13. Victory (reprise)

>>>>sung by the Seigaku & Fudomine Regulars

14. Omae wa Seigaku no Hashira ni Nare

>>>>sung by Takigawa Eiji & Kimeru [Tezuka & Echizen]

15. Challenge ~ Subete wa Shouri no Tame ni (reprise)

>>>>sung by the Seigaku & Fudomine Regulars

16. Victory ~ Omae wa Seigaku no Hashira ni Nare

>>>>sung by the Seigaku Regulars

*17. You Got Game

>>>>sung by Kimeru (if you're a PoT fan, you should recognize this as the first ending song of the anime)

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Cast and Music List from Wikipedia (yes, unreliable as it sometimes is, this is right on point).